文献类型：期刊文献

中文题名：四(对羟基苯基)卟啉镍与meso-四(2-羧甲氧基苯基)卟啉镍的合成及电化学性质研究

英文题名：Synthesis and Electrochemical Behavior of Nickel Porphyrins

作者：刘雄[1];林湘[1]

第一作者：刘雄

机构：[1]甘肃中医学院教务处,甘肃兰州730000

第一机构：甘肃中医药大学教务处（招生办公室、考试中心)

年份：2000

卷号：14

期号：2

起止页码：61

中文期刊名：甘肃教育学院学报（自然科学版）

外文期刊名：Journal of Gansu Education College(Natural Science Edition)

语种：中文

中文关键词：卟啉镍;合成;电化学性质;循环伏安法;对羟基苯基

外文关键词：nickel porphyrin; synthesis; electrochemical property

摘要：合成了四 (对羟基苯基 )卟啉镍与 meso-四 (2 -羧甲氧基苯基 )卟啉镍 ,并用循环伏安法研究了两种金属卟啉的电化学性质 。
Tetra(4 hydroxyphenyl) porphrin was synthesized by condensation of 4 hydroxybenzaldehyde and pyrrole in DMF using anhydrous AlCl 3 as catalyst without necessity to us inert gas for protection. Its nickel complex and Ni meso tetra[2 (carboxymethylenoxy)phenyl] porphyrin were also prepared. The electrochmeical property of TCMOPPNi was also prepared. The electrochemical property of TCMPOPPNi has been investigated in DMSO by cyclic voltammetry and differential pulse voltammetry.