文献类型：期刊文献

中文题名：不同脱水方式对瓜尔胶基多孔复合高吸水凝胶溶胀性能的影响

英文题名：Effect of Dehydrating Methods on the Swelling Properties of the Porous Guar Gum-Based Superabsorbent Composite

作者：施小宁[1,2];王爱勤[2]

第一作者：施小宁

通信作者：Shi, Xiaoning

机构：[1]甘肃中医药大学理学部,甘肃兰州730000;[2]中国科学院兰州化学物理研究所,甘肃兰州730000

第一机构：甘肃中医药大学

通信机构：[1]Science Teaching Department of Gansu University of Chinese Medicine, Lanzhou, 730000, China

年份：2015

卷号：31

期号：10

起止页码：87

中文期刊名：高分子材料科学与工程

外文期刊名：Polymer Materials Science & Engineering

收录：CSTPCD;;EI(收录号：20154801606012);Scopus(收录号：2-s2.0-84947751734);北大核心:【北大核心2014】；CSCD:【CSCD2015_2016】；

基金：甘肃省科技计划资助项目(148RJZA074);甘肃中医学院引进人才科研启动项目(BH2012-095);国家863现代农业技术节水专项(2006AA10021)

语种：中文

中文关键词：瓜尔胶;多孔;复合高吸水凝胶;脱水方式;溶胀性能

外文关键词：guar gum;pores;superabsorbent composite;dehydrating methods;swelling properties

摘要：以十二烷基苯磺酸钠(SDS)胶束作为孔模板,水溶液中瓜尔胶(GG)、丙烯酸(AA)和凹凸棒粘土(APT)接枝聚合制备了瓜尔胶-g-聚丙烯酸钠/凹凸棒粘土(GG-g-PNaA/APT)复合高吸水凝胶,考察了甲醇、乙醇、丙酮脱水溶剂及冷冻过程对复合凝胶平衡溶胀倍率和溶胀速率的影响。扫描电镜表征表明,结合冷冻-甲醇脱水,复合凝胶表面呈蜂窝状的均匀多孔结构。甲醇、乙醇、丙酮脱水对复合凝胶溶胀性能影响顺序为甲醇>乙醇>丙酮。以甲醇脱水为例,结合冷冻过程,可使复合凝胶的初始溶胀速率常数(Kis)从11.4771g/(g·s)提高到17.6336g/(g·s),提高了53.6%。冷冻-甲醇脱水是一种简便的洗除SDS胶束、保持网络孔形貌,提高凝胶溶胀性能的干燥方式。
Using the self-assembled anionic surfactant sodium n-dodecyl sulfonate（SDS）micelles as porous templating,a novel guar gum-g-poly（sodium acrylate）/attapulgite（GG-g-NaA/APT）superporous composite was prepared by the grafting copolymerization of guar gum（GG）,acrylic acid（AA）and attapulgite（APT）in aqueous solution.The investigation of dehydrating solvent,methanol,ethanol,acetone,and freezing procedure on the equilibrium swelling ratio and swelling rate of the porous superabsorbent composite were carried out.SEM demonstrates that the morphologies of the composite,which are dehydrated by freezing-methanol procedure,display homogeneous and well-defined pore.The effect of methanol,ethanol and acetone dehydration on the swelling properties of the composite is the following order：methanol〉 ethanol〉acetone.For freezing-methanol dehydrating composite,the initial swelling rate constant（Kis）in distilled water is improved from 11.4771g/（g·s）to 17.6336g/（g·s）,and enhanced 53.6%.The obtained superporous superabsorbent composite displays rapid salt,pH stimuli-responsiveness,which can be used as drug release material and metal ions absorption.Freezing-methanol dehydration is a simple procedure for washing SDS micelles and keeping the superporous structure in the superabsorbent composite 3Dnetwork.