文献类型：期刊文献

中文题名：4,5-二氮杂芴-9-苯亚胺的电化学性质研究

英文题名：Electrochemical properties of 4,5-diaza-9-phenyl imino fluorine

作者：谈春霞[1];冯若飞[2]

第一作者：谈春霞

机构：[1]甘肃中医学院公共课部,甘肃兰州730000;[2]西北民族大学生物工程与技术国家民委重点实验室,甘肃兰州730000

第一机构：甘肃中医药大学

年份：2009

期号：11

起止页码：1617

中文期刊名：应用化工

外文期刊名：Applied Chemical Industry

收录：CSTPCD;;CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：4,5-二氮杂芴-9-酮;4,5-二氮杂芴-9-苯亚胺;电化学性质

外文关键词：4,5-diazafluoren-9-one ; 4,5-diaza-9-phenyl imino fluorine ; electrochemical properties

摘要：由化合物邻菲啰啉及苯胺合成了4,5-二氮杂芴-9-酮和4,5-二氮杂芴-9-苯亚胺,它们的结构由IR及1H NMR谱、元素分析得以确认,并且通过紫外光谱法、循环伏安法等对其电化学行为进行了测试,结果表明,这些化合物具有较高的电子亲和势和电离势,说明他们的电子传输性能优良。
4,5-Diaza-9-phenyl imino fluorine was synthesized by the condensation of 4,5-diazafluoren-9- one with aniline. The compound of 4,5-diazafluoren-9-one was obtained by oxidation of 1,10-phenanthro- line. Their structures were confirmed by IR, 1H NMR spectroscopies and elemental analysis. The electro- chemical behavior of the product was also studied by UV and cyclic voltammogram. The results show that they have high performance of electron-transporting and hole-blocking ability.