文献类型：期刊文献

英文题名：Visible light driven photoredox/nickel-catalyzed stereoselective synthesis of Z- or E-vinyl thioethers from thiosilane and terminal alkynes

作者：Liu, Hongqiang[1]; Li, Wenjing[1]; Xu, Xia[1]; Yang, Meiding[1]; Han, Deman[1]; Yang, Xiujuan[2]

第一作者：Liu, Hongqiang

机构：[1] School of Pharmaceutical, Chemical and Materials Engineering, Taizhou University, Taizhou, 318000, China; [2] Gansu University of Chinese Medicine, China

第一机构：School of Pharmaceutical, Chemical and Materials Engineering, Taizhou University, Taizhou, 318000, China

通信机构：[1]School of Pharmaceutical, Chemical and Materials Engineering, Taizhou University, Taizhou, 318000, China;[1]School of Pharmaceutical, Chemical and Materials Engineering, Taizhou University, Taizhou, 318000, China;[1]School of Pharmaceutical, Chemical and Materials Engineering, Taizhou University, Taizhou, 318000, China;[2]Gansu University of Chinese Medicine, China|[10735]甘肃中医药大学;

年份：2024

卷号：22

期号：27

起止页码：5524

外文期刊名：Organic and Biomolecular Chemistry

收录：EI(收录号：20242616303490);Scopus(收录号：2-s2.0-85196533617)

语种：英文

外文关键词：Hydrocarbons

摘要：A new method for the synthesis of anti-Markovnikov Z- or E-vinyl thioethers from thiosilane and terminal alkynes under visible-light-induced photoredox/nickel dual catalysis conditions is described. With a judicious choice of a simple nickel catalyst and a ligand, this strategy enables efficient and divergent access to both Z- or E-vinyl thioethers from the same set of simple starting materials. Notably, the approach is free of odorous thiol and has excellent compatibility with functional groups and substrate scope. ? 2024 The Royal Society of Chemistry.