文献类型：期刊文献

英文题名：Visible light driven photoredox/nickel-catalyzed stereoselective synthesis of Z- or E-vinyl thioethers from thiosilane and terminal alkynes

作者：Liu, Hongqiang[1];Li, Wenjing[1];Xu, Xia[1];Yang, Meiding[1];Han, Deman[1];Yang, Xiujuan[2]

第一作者：Liu, Hongqiang

通信作者：Liu, HQ[1];Yang, XJ[2]

机构：[1]Taizhou Univ, Sch Pharmaceut Chem & Mat Engn, Taizhou 318000, Peoples R China;[2]Gansu Univ Chinese Med, Gansu, Peoples R China

第一机构：Taizhou Univ, Sch Pharmaceut Chem & Mat Engn, Taizhou 318000, Peoples R China

通信机构：[1]corresponding author), Taizhou Univ, Sch Pharmaceut Chem & Mat Engn, Taizhou 318000, Peoples R China;[2]corresponding author), Gansu Univ Chinese Med, Gansu, Peoples R China.|[10735]甘肃中医药大学;

年份：2024

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:001250963700001)，CCR-EXPANDED(收录号:WOS:001250963700001)】；

基金：We thank the National Natural Science Foundation of China (No. 21976129) for financial support.

语种：英文

摘要：A new method for the synthesis of anti-Markovnikov Z- or E-vinyl thioethers from thiosilane and terminal alkynes under visible-light-induced photoredox/nickel dual catalysis conditions is described. With a judicious choice of a simple nickel catalyst and a ligand, this strategy enables efficient and divergent access to both Z- or E-vinyl thioethers from the same set of simple starting materials. Notably, the approach is free of odorous thiol and has excellent compatibility with functional groups and substrate scope.