详细信息
电导法测定阳离子型表面活性剂临界胶束浓度实验研究 被引量:8
Experimental Study on the Critical Micelle Concentration of Cationic Surfactant with Conductivity Method
文献类型:期刊文献
中文题名:电导法测定阳离子型表面活性剂临界胶束浓度实验研究
英文题名:Experimental Study on the Critical Micelle Concentration of Cationic Surfactant with Conductivity Method
作者:赵明[1];杨声[1];孙永军[1];李芳蓉[1];李春新[2];王英[1]
第一作者:赵明
机构:[1]甘肃省定西师范高等专科学校,甘肃安西743000;[2]甘肃省化工研究院,甘肃兰州7330020
第一机构:甘肃中医药大学定西校区
年份:2015
卷号:56
期号:3
起止页码:143
中文期刊名:化学世界
外文期刊名:Chemical World
收录:CSCD:【CSCD_E2015_2016】;
基金:2012年度甘肃省高校研究生导师科研项目(1219-02)
语种:中文
中文关键词:电导法;表面活性剂;临界胶束浓度;长碳链烷基季铵盐
外文关键词:conductance method; surface active agent; critical micelle concentration; long carbon chain alkyl quaternary ammonium salts
摘要:采用电导法测定一定温度下不同浓度的十四烷基三甲基氯化铵(TTAC),十六烷基三甲基氯化铵(CTAC),十八烷基三甲基氯化铵(STAC)溶液的电导率值,计算摩尔电导率,研究碳链上碳原子数对表面活性剂临界胶束浓度(CMC)的影响。结果表明:CMC(TTAC)=0.00580 mol/L,CMC(CTAC)=0.0041mol/L,CMC(STAC)=0.0039 mol/L,可知随着碳链上碳原子个数的增多,相应的临界胶束浓度(CMC)呈减小趋势。
Conductance method was used to determine the conductively of myristyl trimethyl ammonium chloride(TTAC),hexadecyl trimethyl ammonium chloride(CTAC)and octadecyl trimethyl ammonium chloride(STAC)solutions with different concentrations at a certain temperature,and their conductivity was calcutated the influence of the number of carbon atoms in the chain on the critical micelle concentration(CMC)of the surfactant was studied.The results showed that the CMC(TTAC)= 0.00580 mol/L,CMC(CTAC)=0.0041mol/L,CMC(STAC)=0.0039mol/L,indicating that the critical micelle concentration(CMC)was decreased with the increase of carbon number in the chain.
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